Reconstruction of Two-Dimensional Spectra from One-Dimensional Projections—Examples from Solid State NMR

Bibhuti B Das, Ramanathan K.V.

Abstract


The use of Projection Reconstruction (PR) to obtain two dimensional(2D) spectra from one-dimensional (1D) data in the solidstate is illustrated. The method exploits multiple 1D spectra obtained using magic angle spinning and off-magic angle spinning. The spectra recorded under the influence of scaled heteronuclear scalar and dipolar couplings in the presence of homonuclear dipolar decoupling sequences have been used to reconstruct J/D Resolved 2D-NMR spectra. The useof just two 1D spectra is observed sufficient to reconstruct a J-resolved 2D-spectrum while a Separated Local Field (SLF) 2D-NMR spectrum could be obtained from three 1D spectra. The experimental techniques forrecording the 1D spectra and procedure of reconstruction are discussedand the reconstructed results are compared with 2D experiments recorded in traditional methods. The application of the technique has been madeto a solid polycrystalline sample and to a uniaxially oriented liquidcrystal. Implementation of PR-NMR in solid state provides high-resolution spectra as well as leads to significant reduction in experimental time.The experiments are relatively simple and are devoid of several technical complications involved in performing the 2D experiments.

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